n-Butyl Acetate Storage & Tank Compatibility
Storing n-Butyl Acetate? Start Here
n-Butyl acetate (C6H12O2) is a clear, colorless ester solvent with a sweet, fruity odor, widely used in lacquers, coatings, adhesives, printing inks, and as an extraction and process solvent. Its balanced evaporation rate and strong solvency for resins make it a workhorse in finishing operations. As a flammable liquid with a flash point near 72 F, it requires bonded, grounded, and vapor-controlled handling. From a containment standpoint, n-butyl acetate is an aggressive organic solvent: like other esters it swells and stress-cracks polyethylene and polypropylene over time. Reliable storage therefore relies on stainless steel or fluoropolymer-lined tanks rather than standard polyethylene or polypropylene vessels, and seals should be PTFE or PVDF rather than nitrile or EPDM. This page summarizes verified identity, hazard, and material-compatibility data, drawn from PubChem and CAMEO Chemicals, to guide safe tank and seal selection for this aggressive ester solvent.
Is n-Butyl Acetate Compatible with Polyethylene (HDPE / XLPE) Tanks?
No. n-Butyl acetate is an ester solvent, and esters are a known incompatibility class for polyethylene. Both HDPE and crosslinked polyethylene (XLPE) absorb the solvent, which causes swelling, softening, loss of mechanical strength, and environmental stress cracking over time. Even where short-term contact appears tolerable, long-term storage in polyethylene is not recommended and is rated Unsuitable (U) on standard chemical resistance charts. Polypropylene is likewise attacked. For bulk or long-term storage, use stainless steel (304 or 316) or fluoropolymer-lined steel. Seals and gaskets should be PTFE or PVDF; avoid EPDM and nitrile, which degrade rapidly in this solvent.
Material compatibility at a glance
Store n-butyl acetate in stainless steel (304/316) or fluoropolymer-lined vessels. Polyethylene (HDPE and XLPE) and polypropylene are not suitable because ester solvents swell and stress-crack these resins. Use PTFE or PVDF for seals and linings; avoid EPDM and nitrile elastomers.
| Material | Rating | Note |
|---|---|---|
| HDPE / XLPE | U | Ester solvents swell, soften, and stress-crack polyethylene; not recommended for storage. |
| Polypropylene (PP) | U | Attacked and softened by ester solvents; not a suitable barrier. |
| 304 / 316 Stainless Steel | S | Standard choice for ester solvents; resists corrosion and solvent attack. |
| Carbon Steel | C | Generally usable when dry; trace water can promote acetic acid formation and corrosion. |
| PTFE / PVDF | S | Fluoropolymers are fully resistant; ideal for gaskets, linings, and seals. |
| FKM (Viton) Elastomer | C | Performs better than most elastomers but can swell; verify the specific grade. |
| EPDM / Buna-N (Nitrile) | U | Swells and degrades rapidly in ester solvents; do not use for seals or hose. |
Ratings: S suitable · C conditional / limited · U unsuitable. Verify against the cited resistance charts and your concentration/temperature before specifying.
The safety that actually matters
- Flammable liquid (NFPA flammability 3, flash point about 72 F): keep away from heat, sparks, open flame, and hot surfaces; no smoking.
- Bond and ground all containers and transfer equipment to prevent static-discharge ignition; vapors are heavier than air and can travel to an ignition source.
- Provide local exhaust ventilation; vapors may cause drowsiness, dizziness, and respiratory irritation (H336, H335-type effects).
- Wear chemical splash goggles and solvent-resistant gloves; the liquid causes serious eye irritation (H319).
- Store in a cool, well-ventilated area away from strong oxidizers, strong acids, and strong caustics; keep containers tightly closed.
- Harmful to aquatic life (H412): prevent releases to soil, drains, and waterways; have spill containment ready.
Common questions
- Can I store n-butyl acetate in an HDPE or XLPE poly tank?
- No. As an ester solvent it swells and stress-cracks polyethylene, so both HDPE and XLPE are rated Unsuitable. Use stainless steel or a fluoropolymer-lined tank instead.
- What tank material is best for n-butyl acetate?
- 304 or 316 stainless steel is the standard choice. Fluoropolymer (PTFE/PVDF) linings are also fully resistant and are ideal for seals, gaskets, and tank linings.
- Is n-butyl acetate flammable?
- Yes. It has a closed-cup flash point near 72 F and an NFPA flammability rating of 3. Keep it away from ignition sources and use bonded, grounded, vapor-controlled handling.
- What seal and gasket materials work with n-butyl acetate?
- PTFE and PVDF are fully compatible. FKM (Viton) is usable but can swell, so verify the grade. EPDM and nitrile (Buna-N) degrade quickly and should not be used.
How we build n-Butyl Acetate storage
n-Butyl Acetate is a flammable solvent that permeates polyethylene. It is built in listed steel or stainless, bonded and grounded.
Sources & References
All compatibility ratings, hazard classifications, and chemical identifiers on this page are sourced from authoritative third-party publications. Verify against the original references before final specification.
- PubChem Compound Summary: Butyl acetate (CID 31272) — Authoritative identity record: CAS 123-86-4, formula C6H12O2, MW 116.16, InChIKey DKPFZGUDAPQIHT-UHFFFAOYSA-N, plus GHS and physical-property data. pubchem.ncbi.nlm.nih.gov
- CAMEO Chemicals (NOAA): Butyl Acetate — Source for NFPA 704 ratings (Health 2, Flammability 3, Instability 0) and physical properties including 72 F flash point and 0.875 specific gravity. cameochemicals.noaa.gov
- PubChem Laboratory Chemical Safety Summary (LCSS): Butyl acetate — Curated GHS hazard classification, signal word, and hazard statements (H226 flammable; H319 eye irritation; H336 drowsiness/dizziness). pubchem.ncbi.nlm.nih.gov
- UN GHS (Rev. 10): Globally Harmonized System of Classification and Labelling of Chemicals — Defines the H-code statements and pictogram/signal-word logic used for the flammable-liquid and STOT single-exposure hazards cited here. unece.org
- Chemical Resistance Guide for High Density Polyethylene (HDPE/LLDPE) — Polyethylene chemical resistance chart confirming that ester solvents such as butyl acetate are not recommended (Unsuitable) for HDPE/XLPE storage. www.cole-parmer.com
- NIOSH Pocket Guide to Chemical Hazards: n-Butyl acetate — Occupational exposure limits, flammability, incompatibilities (strong oxidizers, acids, alkalis), and target-organ effects for safe handling. www.cdc.gov