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Ultramarine Blue Storage & Tank Compatibility

Storing Ultramarine Blue? Start Here

Ultramarine Blue (C.I. Pigment Blue 29, CAS 57455-37-5) is a brilliant, lightfast inorganic pigment built on a sodium aluminosilicate sulfur framework, formula Al6Na8O24S3Si6. It is the synthetic equivalent of the mineral lazurite and is prized for its pure blue shade, heat stability, and chemical inertness. The pigment is handled as a fine dry powder and as neutral aqueous slurries across plastics, coatings, paper, detergent, cosmetic, and rubber applications. Because it is insoluble in water and carries no solvent, oxidizer, or acid activity, ultramarine blue is one of the most storage-friendly colorants for polyethylene tank systems. The one handling rule that governs material selection is acid avoidance: contact with acids liberates hydrogen sulfide gas, so the pigment and any acidic process streams must be kept fully segregated.

Is Ultramarine Blue Safe to Store in HDPE or XLPE Tanks?

Yes. Ultramarine Blue is rated Suitable (S) for both HDPE and crosslinked polyethylene (XLPE) tanks. It is an inert, water-insoluble mineral pigment - there is no aggressive solvent, no oxidizing power, and no acidity in the material itself to degrade the polyethylene matrix. Dry powder, dispersions, and neutral aqueous slurries (typical pH 7 to 9) all store cleanly in polyethylene with no swelling, stress cracking, or chemical attack. The pigment is non-combustible and thermally stable to well above normal storage temperatures.

The compatibility caveat is not about the tank wall but about co-storage: ultramarine blue must never share containment, fittings, or transfer lines with acids, because acid contact releases toxic hydrogen sulfide. Keep acidic chemicals on separate systems, choose chemically resistant gaskets matched to any slurry dispersant, and the polyethylene tank itself will give long, trouble-free service.

Material compatibility at a glance

Ultramarine Blue is an inert, insoluble inorganic mineral pigment, which makes it well matched to polyethylene storage. HDPE and crosslinked polyethylene (XLPE) tanks are recommended for both the dry powder and neutral aqueous slurries: there is no solvent, oxidizer, or acid character in the pigment to attack the polymer chain. Polypropylene, 316 stainless steel, and EPDM elastomers are likewise suitable for neutral service. The single critical rule is acid segregation - contact with acids liberates hydrogen sulfide gas - so carbon steel and any shared lines with acidic media must be kept apart. Verify gasket and pump elastomers against the specific dispersant chemistry of slurry grades.

MaterialRatingNote
HDPE / XLPESRecommended for ultramarine blue powder and aqueous/neutral slurries; the pigment is an inert insoluble mineral with no solvent or oxidizer action on polyethylene.
Polypropylene (PP)SCompatible with neutral pigment slurries and dispersions; good general resistance to inorganic mineral solids.
316 Stainless SteelSCompatible; no chloride or acid attack from the neutral pigment itself.
Carbon SteelCAcceptable for dry powder service; protect from moisture and never co-store with acids that could generate hydrogen sulfide.
EPDM (gaskets/seals)SSuitable for neutral aqueous slurries and dispersions.
Viton (FKM)CGenerally acceptable; confirm against the specific carrier or dispersant in the slurry formulation.
Concentrated Acids (contact)UDo not store or mix with acids - contact liberates toxic hydrogen sulfide gas; keep acid streams fully segregated.

Ratings: S suitable · C conditional / limited · U unsuitable. Verify against the cited resistance charts and your concentration/temperature before specifying.

The safety that actually matters

  • Keep ultramarine blue strictly away from acids - acid contact liberates hydrogen sulfide, a toxic, flammable gas; segregate acidic chemicals in storage and piping.
  • Control airborne dust during powder handling; use local exhaust ventilation and a dust mask to avoid respiratory irritation. Fine powder dispersed in air can form a combustible dust hazard.
  • Avoid heating above roughly 440 C in air - an exothermic reaction can evolve sulfur dioxide.
  • Wear gloves and eye protection; the pigment can stain skin and may cause mild eye or skin irritation on prolonged contact.
  • Store in a cool, dry, well-ventilated area in closed containers, away from incompatible acids and strong oxidizers.
  • Always consult the supplier's current Safety Data Sheet for the specific grade before handling.

Common questions

Can Ultramarine Blue be stored in a polyethylene tank?
Yes. As an inert, insoluble mineral pigment with no solvent or oxidizer action, ultramarine blue is rated Suitable (S) for HDPE and XLPE tanks in powder, dispersion, and neutral slurry form. The polyethylene wall is not attacked under normal storage conditions.
Is Ultramarine Blue a hazardous chemical?
Under GHS it is not classified - there is no signal word and no hazard (H) codes for the pure pigment. Its NFPA 704 profile is low (Health 1, Flammability 0, Reactivity 0). The key practical hazard is that acid contact releases toxic hydrogen sulfide gas, so acids must be kept away.
Why must Ultramarine Blue be kept away from acids?
The pigment's sulfur-containing aluminosilicate structure reacts with acids to liberate hydrogen sulfide, a toxic and flammable gas. Acid segregation is the single most important storage and material-selection rule for this pigment.
Does Ultramarine Blue dissolve in water?
No. It is insoluble in water and is handled as a dry powder or as a stable neutral aqueous slurry (pH about 7 to 9). Its insolubility is one reason it stores so cleanly in polyethylene.

Designing the storage system, not just picking a tank?

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Sources & References

All compatibility ratings, hazard classifications, and chemical identifiers on this page are sourced from authoritative third-party publications. Verify against the original references before final specification.

  1. PubChem CID 71587188 - Ultramarine Blue (C.I. Pigment Blue 29) — Canonical identity record: CAS 57455-37-5, formula Al6Na8O24S3Si6, InChIKey IRERQBUNZFJFGC-UHFFFAOYSA-L, synonyms including C.I. 77007 and lazurite. pubchem.ncbi.nlm.nih.gov
  2. GELEST Ultramarine Blue HS Safety Data Sheet (CAS 57455-37-5) — GHS-US: Not classified (no label, no signal word). Section 9: blue powder, insoluble in water, specific gravity 2.25-2.35, melting point greater than 400 C. Section 10: contact with acids liberates hydrogen sulfide; incompatible materials = acids. www.gelest.com
  3. Langridge Ultramarine Blue Pigment Safety Data Sheet (Pigment Blue 29) — Non-hazardous, non-combustible blue powder; density 2.35, melting point greater than 1000 C, slurry pH 7-9, insoluble in water; incompatible with oxidizing agents. langridgecolours.com
  4. United Nations GHS (Purple Book) - Classification Criteria — Globally Harmonized System framework against which ultramarine blue is assessed as not meeting any hazard class for the pure substance. unece.org
  5. NFPA 704 - Standard System for the Identification of the Hazards of Materials — Defines the Health / Flammability / Reactivity diamond; ultramarine blue rates low across all three as a non-combustible, stable inorganic pigment (Health 1, Flammability 0, Reactivity 0). www.nfpa.org
  6. Chemical Resistance Guide for Polyethylene (HDPE/XLPE) Storage Tanks — Polyethylene resistance chart: inert insoluble mineral pigments and neutral aqueous slurries are rated Suitable for HDPE and crosslinked polyethylene; strong acids and oxidizers are the limiting incompatibilities. www.poly-tank.com