Diethylene Glycol Monobutyl Ether (Butyl Carbitol) Storage & Tank Compatibility
Storing Diethylene Glycol Monobutyl Ether (Butyl Carbitol)? Start Here
Diethylene glycol monobutyl ether, widely sold as butyl carbitol or butyl diglycol, is the n-butyl ether of diethylene glycol with the formula C8H18O3. It is a colorless liquid with a mild, pleasant odor that is fully miscible with water and most organic solvents, which is why it is so common in surface coatings, cleaners, hydraulic fluids, printing inks, and coalescing agents for latex paints. The molecule pairs two ether linkages with a terminal hydroxyl group, giving it solvency for resins and oils alongside compatibility with water-based systems. With a high boiling point near 230 C and a very low vapor pressure, it evaporates slowly and stays in the liquid phase across normal storage temperatures, making it a frequent bulk solvent that fabricators need to store safely. Because it oxidizes in air to form unstable peroxides and can damage organs on prolonged exposure, containment, ventilation, and correct tank selection all matter at volume.
Storing Diethylene Glycol Monobutyl Ether in HDPE and XLPE Tanks
Polyethylene is a reasonable, common choice for diethylene glycol monobutyl ether because it is an oxygenated, water-miscible glycol ether rather than an aggressive aromatic, chlorinated, ketone, or strong-oxidizer solvent. Published polyethylene resistance charts generally rate butyl carbitol and similar glycol ethers as good or satisfactory in HDPE and crosslinked polyethylene at ambient temperature, which is why we list HDPE / XLPE as Conditional rather than fully recommended. The honest caveats matter: the compound forms unstable peroxides on exposure to air and light, and elevated temperature increases the tendency of any solvent to swell or soften a polymer over time. For that reason, store near ambient temperature, confirm the specific tank resin and gasket grade against the manufacturer's chemical resistance data, and keep the tank closed and dry to limit peroxide formation. Used within those limits, a quality PE tank with compatible fittings is a practical and economical option for this solvent.
Material compatibility at a glance
Diethylene glycol monobutyl ether (butyl carbitol) is a high-boiling, water-miscible glycol ether solvent that polyethylene (HDPE and XLPE) generally tolerates at ambient temperature, making a quality PE tank a practical storage option once grade and temperature are confirmed. 316 stainless steel and Viton (FKM) are dependable for wetted metal and elastomer parts. Because the compound forms peroxides on exposure to air and light, keep vessels closed and dry and avoid prolonged storage of opened containers. Confirm aluminum, carbon steel, and elastomer choices against supplier resistance data before committing.
| Material | Rating | Note |
|---|---|---|
| HDPE / XLPE | C | As an oxygenated, water-miscible glycol ether, butyl carbitol is generally handled by polyethylene at ambient temperature; published PE resistance charts rate glycol ethers good to satisfactory. Confirm the specific resin and gasket grade and keep storage near ambient before committing. |
| Polypropylene (PP) | C | Comparable to PE for this high-boiling oxygenated solvent at ambient temperature; verify against supplier resistance data for sustained contact. |
| 316 Stainless Steel | S | Standard choice for glycol ether service; resists this solvent well across normal handling temperatures. |
| Carbon Steel | C | Usable for the solvent itself, but CAMEO notes it can react with carboxylic acids, strong reducers, and oxidizers and forms peroxides in air; keep tanks closed and dry. |
| Aluminum | C | Glycol ethers can react with some metals; confirm against supplier data and avoid for long-term wetted parts if uncertain. |
| EPDM Elastomer | C | Often serviceable with glycol ethers; confirm the specific compound, since these solvents can attack some rubbers. |
| Viton (FKM) | S | Broadly resistant to glycol ether solvents; a reliable seal and gasket choice. |
Ratings: S suitable · C conditional / limited · U unsuitable. Verify against the cited resistance charts and your concentration/temperature before specifying.
The safety that actually matters
- Treat butyl carbitol as a target-organ hazard; the GHS classification includes may cause damage to organs (H371) and causes damage to organs through prolonged or repeated exposure (H372), so use chemical-resistant gloves, splash goggles, and adequate ventilation.
- It is a combustible liquid (flash point about 78 C / 172 F); keep it away from heat, sparks, and open flame and bond and ground containers during transfer.
- The solvent oxidizes readily in air to form unstable peroxides that may explode spontaneously; store in closed, shaded containers, keep it dry, and avoid long-term storage of opened drums.
- Avoid contact with strong oxidizers, strong reducing agents, alkali metals, and carboxylic acids, all of which can react with the material.
- Provide eyewash and emergency shower access; the material causes serious eye irritation (H319) and may cause drowsiness or dizziness (H336).
- Confirm tank, gasket, and fitting compatibility before filling, and keep storage near ambient temperature for the most reliable polyethylene service.
Common questions
- Can I store diethylene glycol monobutyl ether in an HDPE or XLPE tank?
- Generally yes at ambient temperature. As an oxygenated, water-miscible glycol ether, butyl carbitol is usually rated good or satisfactory in polyethylene, which is why we mark HDPE / XLPE as Conditional. Verify the specific resin and gasket grade against supplier resistance data and keep storage near ambient temperature and dry before committing.
- What is the NFPA 704 rating for diethylene glycol monobutyl ether?
- Per CAMEO Chemicals, the ratings are Health 1, Flammability 2, and Instability 1, with no special hazard. The Instability 1 reflects that the compound oxidizes in air to form unstable peroxides that may explode spontaneously.
- Is diethylene glycol monobutyl ether flammable?
- It is a combustible liquid with a flash point near 78 C (172 F), earning an NFPA flammability rating of 2. It needs significant heating before it will ignite, but you should still keep it away from heat, sparks, and flame.
- What materials should I avoid with diethylene glycol monobutyl ether?
- Avoid strong oxidizers, strong reducing agents, alkali metals, and carboxylic acids. Confirm elastomer choices too, since glycol ethers can attack some rubbers; 316 stainless steel and Viton (FKM) are dependable options for wetted parts.
Designing the storage system, not just picking a tank?
Vendor-neutral engineering guides from our custom fabrication team - material of construction, containment, and code, matched to your chemistry.
Explore: FRP & Fiberglass Tanks · Double Wall Tanks · Solvent Recovery · Custom Fabrication Hub
Sources & References
All compatibility ratings, hazard classifications, and chemical identifiers on this page are sourced from authoritative third-party publications. Verify against the original references before final specification.
- PubChem Compound Summary - Diethylene Glycol Monobutyl Ether (CID 8177) — Authoritative identity: CAS 112-34-5, formula C8H18O3, molecular weight 162.23, IUPAC name 2-(2-butoxyethoxy)ethanol, InChIKey OAYXUHPQHDHDDZ-UHFFFAOYSA-N, plus GHS classification and synonyms (butyl carbitol, butyl diglycol). pubchem.ncbi.nlm.nih.gov
- CAMEO Chemicals (NOAA) - Diethylene Glycol Monobutyl Ether — NFPA 704 ratings (Health 1, Flammability 2, Instability 1); flash point 172 F; boiling point 448 F; density 0.954; miscible with water; reactivity notes including peroxide formation in air and reaction with alkali metals, oxidizers, reducers, and carboxylic acids. cameochemicals.noaa.gov
- NFPA 704: Standard System for the Identification of the Hazards of Materials for Emergency Response — Defines the health, flammability, and instability diamond rating scale (0-4) used to communicate the 1-2-1 profile cited for this solvent. www.nfpa.org
- UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS) — Source standard for the H-code hazard statements and Warning signal word listed for diethylene glycol monobutyl ether. unece.org
- Professional Plastics - HDPE and LDPE Chemical Resistance Chart — Polyethylene resistance reference used to assess glycol ether solvents; supports a generally good/satisfactory ambient-temperature rating, consistent with the Conditional HDPE / XLPE verdict. www.professionalplastics.com
- INEOS HDPE Chemical Resistance Guide — Manufacturer polyethylene resistance data corroborating that oxygenated glycol-type solvents are handled by HDPE at ambient temperature. www.ineos.com