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Isopropanolamine (Monoisopropanolamine, MIPA) Storage & Tank Compatibility

Storing Isopropanolamine (Monoisopropanolamine, MIPA)? Start Here

Isopropanolamine, also called monoisopropanolamine or MIPA (C3H9NO), is a colorless, water-miscible alkanolamine that combines a basic amine group with a secondary alcohol. That dual chemistry makes it a versatile acid-gas absorbent, neutralizer, and intermediate. Industry uses it to scrub hydrogen sulfide and carbon dioxide from gas streams, to neutralize fatty acids in metalworking and cutting fluids, as a pH buffer and corrosion inhibitor in coatings, cleaners, and cement admixtures, and as a building block for surfactants, herbicide salts, and pharmaceuticals. Because it is strongly alkaline and corrosive to skin and eyes, the material of construction matters: the wrong elastomer or a copper-bearing alloy will degrade, contaminate the product, or fail in service. Choosing a tank, gasket, and fitting package that is genuinely rated for amine duty protects both the chemical and the people handling it.

Can you store isopropanolamine in a poly tank?

Yes. Isopropanolamine is compatible with polyethylene. Published resistance charts rate amines, alkanolamines, alcohols, and glycols as Resistant on both HDPE and crosslinked (XLPE) polyethylene at ambient temperature, and aqueous ammonia (a close chemical analog) is likewise rated Resistant. A chemical-service poly tank is a sound, economical choice for bulk MIPA. Specify a tank rated for the fluid’s specific gravity (about 0.96, so standard 1.5 SG tanks are more than adequate), use EPDM gaskets rather than Viton/FKM, and avoid any copper, brass, bronze, or aluminum in wetted hardware. For heated, high-temperature, or high-purity applications, 316 stainless steel is the upgrade path; otherwise quality poly performs well for storage and dispensing.

Material compatibility at a glance

Isopropanolamine is an alkaline alkanolamine that is compatible with chemical-grade HDPE and XLPE polyethylene, polypropylene, and 304/316 stainless steel. Avoid copper alloys, aluminum, and fluoroelastomer (Viton/FKM) seals; specify EPDM gaskets.

MaterialRatingNote
HDPE / XLPESAlkanolamines, amines, alcohols and glycols are listed as Resistant on polyethylene resistance charts. Use a chemical-service poly tank gasketed with EPDM and rated to the fluid specific gravity.
PolypropyleneSResistant to alkanolamines; common for fittings, valves and secondary fabrication.
304 / 316 Stainless SteelSExcellent for heated or high-purity service; 316 preferred where chloride traces are present.
EPDM elastomerSPreferred gasket and seal material for amines.
Viton / FKMUFluoroelastomers are attacked by amines — do not use for gaskets or seals.
Carbon steelCUsable for bulk amine but can discolor product and suffer stress effects; line or passivate for purity-sensitive service.
Copper / brass / bronzeUAmines attack copper alloys; avoid all copper-bearing wetted parts.
AluminumUCorroded by alkaline amines; not recommended.

Ratings: S suitable · C conditional / limited · U unsuitable. Verify against the cited resistance charts and your concentration/temperature before specifying.

The safety that actually matters

  • Corrosive (H314/H318): Causes severe skin burns and serious eye damage — full face shield, chemical goggles, and amine-resistant gloves are mandatory.
  • Harmful by ingestion and skin contact (H302/H312): Avoid swallowing and prevent prolonged or repeated skin exposure.
  • Combustible liquid: Flash point near 77 °C (171 °F); keep away from heat, sparks, and open flame and store in a cool, ventilated area.
  • Strong base: Reacts exothermically with acids; segregate from acids, oxidizers, and isocyanates and add slowly when neutralizing.
  • Vapor and mist: Provide local exhaust; vapor and aerosols irritate the respiratory tract and eyes.
  • Aquatic hazard (H402): Harmful to aquatic life — contain spills and prevent release to drains or surface water.

Common questions

Is isopropanolamine compatible with HDPE and XLPE tanks?
Yes. Polyethylene resistance charts rate amines, alkanolamines, and alcohols as Resistant on HDPE and XLPE at ambient temperature. Use a chemical-service poly tank rated to the fluid specific gravity (about 0.96), with EPDM seals.
What is the NFPA 704 rating for isopropanolamine?
OSHA and NOAA CAMEO Chemicals both list Health 3, Flammability 2, and Instability 0, with no special hazard. It is corrosive and a combustible liquid but normally stable.
Which materials should be avoided with isopropanolamine?
Avoid copper, brass, bronze, and aluminum, which this alkaline amine corrodes, and avoid Viton/FKM elastomer seals, which amines attack. Specify EPDM gaskets and poly, polypropylene, or 316 stainless wetted parts instead.
Is isopropanolamine flammable?
It is a combustible liquid rather than a highly flammable one, with a closed-cup flash point near 77 °C (171 °F). Keep it away from heat and ignition sources and store it cool and ventilated.

Flammable solvent? Think recovery, containment, and grounding.

Flammable and volatile solvents add recovery, vapor, and ignition-control questions on top of material choice. Guides from our fabrication team:

Explore: Solvent Recovery  ·  Double Wall Tanks  ·  Chemical Compatibility

Sources & References

All compatibility ratings, hazard classifications, and chemical identifiers on this page are sourced from authoritative third-party publications. Verify against the original references before final specification.

  1. PubChem CID 4 — 1-Amino-2-propanol (Isopropanolamine) — Authoritative identity record: CAS 78-96-6, formula C3H9NO, MW 75.11, GHS classification and hazard statements. pubchem.ncbi.nlm.nih.gov
  2. OSHA Occupational Chemical Database — 1-Amino-2-propanol (ID 819) — NFPA 704 Health 3 / Fire 2 / Reactivity 0; boiling point 313–316 °F, flash point 171 °F, specific gravity 0.961, vapor pressure 2.59 mm Hg. www.osha.gov
  3. NOAA CAMEO Chemicals — Monoisopropanolamine — Confirms NFPA Health 3 / Flammability 2 / Instability 0; colorless liquid, lighter than water, water-soluble; amine reactivity and incompatibilities. cameochemicals.noaa.gov
  4. United Nations GHS (Rev. 10) — Globally Harmonized System of Classification and Labelling — Source standard for the GHS hazard statements (H302, H312, H314, H318, H402) and the signal word Danger. unece.org
  5. King Plastic Corporation — HDPE Chemical Resistance Chart — Polyethylene resistance chart listing Alcohols, Glycols, aqueous Ammonia and amines as Resistant (R) — supports the poly-compatible verdict for alkanolamines. www.kingplastic.com
  6. March Pump — HDPE Chemical Compatibility Guide — Lists ethanolamine, diethanolamine, triethanolamine, alcohols and glycols against HDPE; corroborates amine/alcohol compatibility with polyethylene. www.marchpump.com
  7. CalPaclab / Cole-Parmer — Polyethylene Chemical Compatibility Chart — Rates amyl/ethyl alcohol, glycols and ammonium hydroxide as Excellent on LDPE/HDPE (little or no damage after 30 days), consistent with poly suitability for this alkanolamine. www.calpaclab.com